I use a vinegar skin toner (50% water)since I stopped using soap on my face. I rince it off with water.
It occured to me Vitamin C might be better and also a similar acid. Here's what I found.
Interesting commentary on oxidization of vitamin c: http://thebeautybrains.com/2008/05/20/how-to-make-diy-cosmetics-with-vitamin-c/
Or Apple Cider Vinegar for AHA peels http://www.essentialdayspa.com/forum/viewthread.php?tid=35403
Here's a recipe thread with all sorts of cosmetics
http://www.essentialdayspa.com/forum/viewthread.php?p=397787
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